Agents say Barnard was selling the synthetic marijuana right over the counter at his convenience store called Super B.
Synthetic marijuana is starting to become popular among teens across the country.
"What they are trying to do is replicate THC. Which is the chemical in marijuana that gives you the high and what they are doing is synthetic producing THC. It's a few molecules off the chemical chain, but it's essentially the same thing," said Pro.
Barnard's partner Tish Fowler was also arrested for selling synthetic marijuana. She is being held in the Decatur County Jail.
Agent Pro thanks all of the departments who lent a hand in bringing down this drug ring. He says the operation could not have been a success without their cooperation.
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